• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    Thermo treatment process for wood comprising the following steps: a. Placing the wood batch to be treated in a treatment chamber; b. Exchanging the atmosphere inside the treatment chamber by evacuating the air, replacing the evacuated air by an inert gas atmosphere in gas form, at 8 to 12 bar pressure; c. Heating the inert gas atmosphere up to 165 to 175 ºC, d. increasing the pressure in the inert gas atmosphere to 14-16 bar; e. maintaining the temperature in step c. and the pressure in step d. for from 90 to 150 minutes; f. cooling the inert gas atmosphere to a temperature of 20 to 35 ºC g. retrieving the treated wood batch
    公开号:DK201670528A1
    申请号:DKP201670528
    申请日:2016-07-15
    公开日:2018-02-19
    发明作者:Peter Klaas
    申请人:Wtt Holding Aps；
    IPC主号:
    专利说明:

    <1θ> DANMARK <1°> DK 2016 70528 A1
    <12> PATENTANSØGNING
    Patent- og
    Varemærkestyrelsen (51) lnt.CI.: B 27 K 3/08(2006.01)
    B 27 K 5/00(2006.01)
    B 27 K 3/34(2006.01)
    B 27 K 3/48(2006.01) (21) Ansøgningsnummer: PA 2016 70528 (22) Indleveringsdato: 2016-07-15 (24) Løbedag: 2016-07-15 (41) Aim. tilgængelig: 2018-01-16 (71) Ansøger: WTT Holding ApS, Jyllandsvej 9, 7330 Brande, Danmark (72) Opfinder: Peter Klaas, Bakkegårdsvej 7, 5390 Martofte, Danmark (74) Fuldmægtig: Patrade A/S, Fredens Torv 3A, 8000 Århus C, Danmark (54) Benævnelse: A thermo treatment process for wood (56) Fremdragne publikationer:
    EP 2998087 A2 US 4377040 A CA 1159643 A JP 2013/180460 A US 2008/0178490 A1 EP 2196295 A1 (57) Sammendrag:
    Thermo treatment process for wood comprising the following steps:
    a. Placing the wood batch to be treated in a treatment chamber;
    b. Exchanging the atmosphere inside the treatment chamber by evacuating the air, replacing the evacuated air by an inert gas atmosphere in gas form, at 8 to 12 bar pressure;
    c. Heating the inert gas atmosphere up to 165 to 175 2C,
    d. increasing the pressure in the inert gas atmosphere to 14-16 bar;
    e. maintaining the temperature in step c. and the pressure in step d. for from 90 to 150 minutes;
    f. cooling the inert gas atmosphere to a temperature of 20 to 35 2C
    g. retrieving the treated wood batch
    Fortsættes ...
    DK 2016 70528 A1
    -8,.808
    u.-xc
    5/.888 wxso w
    o;
    4,808
    2.888
    8+388:
    t i JX i * i i i /* /Or J * /i i λΧΧΧΧΧΧΧΧ· X >
    sxxxxxxxxy £y Y/.· fy
    S SO -OS §0 SO Si<0SS0SWS«OJSOS002S0 tape; js-tufa (Cskiül·;
    , 1
    DK 2016 70528 A1 i
    A thermo treatment process for wood
    Field of the Invention
    The present invention is directed at a thermo treatment process for wood.
    Background of the Invention
    In the art there has been suggested various methods for thermo treatment of wood as will be explained below. The purpose of subjecting wood to a thermo treatment is that it has for a long time been known that by treating wood under a certain temperature regime increasing the temperature for a period of time and thereafter reducing the temperature back to ambient temperature the wood attains some improved qualities. For example the durability as well as the insulating properties of the timber are improved. Taboratory tests have shown that this is due to a structural reordering of the molecular structure of the wood such that the wood from having a more or less random molecular fibre structure due the thermo treatment is reorganized to have a much more structured and linear fibre structure at the molecular level which provides for the improved characteristics.
    These aspects are clearly disclosed and discussed in the “Thermo Wood® Handbook” published by the Finnish Thermo Wood Association in 2003. This book is widely considered as the reference work when it comes to thermo treatment of wood. According to the disclosure the process is divided into three phases where the wood which is placed in a treatment chamber is subjected to an increase inside the treatment chamber in two steps, first up to a temperature of approx. 100°C for a first period and thereafter to a temperature of approx. 130°C for a second period.
    The purpose of the first phase is to dry out the wood and this phase lasts approx. 36 hours. In the second phase the temperature is further increased to between 185°C250°C.
    The elevated temperature is maintained for approx. 16-17 hours in order for the wood to be subjected to the modification process as described above.
    Finally, in the third phase a cooling and moisture conditioning phase is carried out where once the temperature has fallen below 80-90°C, a remoisturing of the wood
    DK 2016 70528 A1 takes place such that the moisture content in the treated and finished wood is in the range of 4-10% by weight. The third phase depending on the type of wood being treated typically takes 18-28 hours.
    Wood mainly consists of three different components, namely hemicelluloses, celluloses and lignin. These materials have different characteristics and as such they react differently during the heat treatment. Hemicelluloses is special in that in the first part of the heating of the wood sample the modification of hemicelluloses is endothermic meaning that heat is transferred and absorbed by the wood until a certain temperature is reached.
    This certain temperature is depending on the type of wood and thereby also the contents of hemicelluloses which varies depending on the species and the growth conditions for that particular species as well as the moisture content and the pressure, but it will typically be around 230°C.
    At this temperature the modification of hemicelluloses turns from an endothermic process to an exothermic process, i.e. more energy is generated than what is added to the hemicelluloses component of the wood. At the same time the celluloses will have been modified and will still he undergoing modification. Typically, the cellulose part of a wood sample will be substantially larger than the hemicelluloses part, and a such a substantial part of the wood has been modified at this stage.
    A number of drawbacks, however, are associated with the prior art methods and procedures.
    Firstly, the procedure takes a very long time thereby reducing the output from a process plant. Typically, a treatment of a batch of wood with prior art methods takes from 24 hours and up to 36 hours depending on the wood and how aggressive the modification process is pursued.
    The very long process time and thereby the low turnover in the machinery naturally increases the cost of the modified wood due to the long process time. Furthermore, traditional modification processes use steam and heated steam in order to increase the
    DK 2016 70528 A1 heat inside the wood and there thereby activate the modification process. As there is already moisture inside the wood and the wood is not absolutely homogenous there will be a non-even distribution of moisture inside the wood and at the same time the wood may not have a completely homogenous structure.
    This does cause problems to the quality of treated wood in that as the moisture inside the wood is heated, steam will be generated and due to the variations both in moisture content and the wood structure as well as the variation of density in the wood to be treated the internal pressure inside the wood due to the heating will cause cracks and other detrimental side effects during the treatment. As the treatment chamber has a relative high steam pressure, the built up pressure inside the wood cannot dissipate slowly, but will eventually cause a small steam explosion, potentially causing cracking or other damage. At the same time miscolouring of the surface may be a result.
    In order to improve this, it has been suggested in JP2013180460 to replace the air and steam inside the treatment chamber by a super critical carbon dioxide atmosphere. Super critical carbon dioxide is in the Japanese reference defined as carbon dioxide beyond a critical point which is described as being 31 °C at 7.4 MPa.
    When the carbon dioxide is in a super critical state, it acts like a fluid and as such together with the very high pressure (above 74 bar) it replaces the moisture inside the wood structure. In order to remove the moisture from the wood it is necessary to further heat the super critical carbon dioxide atmosphere in order to transform moisture, typically water, from its liquid to its gaseous state, i.e. steam. This in turn causes the pressure to increase even more. This process therefore has a number of drawbacks, firstly the vessel in which the process is to be carried out must be extremely strong in order to be able to withstand the very elevated pressure inside the treatment chamber.
    Furthermore, any generation of steam exposed to such a high pressure will have a severely detrimental effect on any imperfections such as cracks, nuts and the like in the wood, thereby causing the wood to crack or split.
    DK 2016 70528 A1
    Object of the Invention
    Consequently, there is a need for a process which is faster and has improved durability characteristics as compared to the prior art methods.
    Description of the Invention
    The invention addresses this by providing a thermo treatment process for wood comprising the following steps:
    a. Placing the wood batch to be treated in a treatment chamber;
    b. Exchanging the atmosphere inside the treatment chamber by evacuating the air, replacing the evacuated air by an inert gas atmosphere in gas form, at 8 to 12 bar pressure;
    c. Heating the inert gas atmosphere up to 165 to 175 °C,
    d. increasing the pressure in the inert gas atmosphere to 14-16 bar;
    e. maintaining the temperature in step c. and the pressure in step d. for from 90 to 150 minutes;
    f. cooling the inert gas atmosphere to a temperature of 20 to 35 °C
    g. retrieving the treated wood batch.
    With this process a relatively low pressure is maintained inside the treatment chamber.
    At the same time, by replacing an atmosphere containing steam by an atmosphere of an inert gas atmosphere, and particularly in a preferred embodiment where the inert gas is nitrogen, the heat exchange capabilities between the treatment atmosphere and the wood is increased substantially. Steam’s heat exchange capabilities are relatively poor up until approx. 140°C, whereas for example for nitrogen its heat exchange capabilities are substantially constant throughout the temperature interval and at the same time much better than what is the case with steam.
    Therefore, it is possible to heat the atmosphere and thereby the wood inside the treatment chamber much faster and the heating process is only limited by the available apparatus for heating the gas and the ability of the heat to travel through the wood such that the core temperature of the wood reaches the desired treatment temperature.
    DK 2016 70528 A1
    Furthermore, as no steam is added there is no steam pressure, and any moisture present in the wood will simply be replaced and absorbed by the inert gas atmosphere without causing steam explosions or other steam expansion processes. Furthermore, due to the difference between the moisture/steam present in the wood and the inert gas preferably nitrogen it is achieved that substantially the entire water based moisture content in the wood is replaced by the inert gas, i.e. is removed from the wood. At the same time due to the temperature increase the modification processes as discussed above specifically with reference to hemicelluloses and celluloses is progressing.
    As the gas also after the modification process is the same and still has the same heat exchange capabilities it is also possible to cool the treatment chamber and thereby the wood very quickly such that an overall improved process is provided with a minimum of process time. Instead of the 36-68 hours for the traditional treatment time, the present invention carries out a full cycle that takes approx. 5-6 hours.
    In a further advantageous embodiment the process in step c and d together takes between 90-110 minutes. These steps may be carried out simultaneously or they may be carried out as independent steps depending on the process equipment available and how the temperature increase is achieved and how the pressure increase is achieved. Even though a very good heat exchange coefficient is present when the atmosphere is replaced with a nitrogen atmosphere it is still necessary to moderate the heat increase in order not to get problems relating to temperature expansion coefficients and the like.
    In a further advantageous embodiment a mineral or organic oil for impregnating the wood may be applied. As the wood at this point is completely dry, all the moisture has been replaced by the inert gas/nitrogen it is possible to make the oil penetrate very deeply into the wood and thereby achieve a very good preservative effect.
    Naturally the mineral or organic oil has to be designed such that the molecule size and structure is able to penetrate the wood structure which is different from species to species and at the same time the mineral oil may be modified with various compounds in order to give long lasting effect, fungicidal properties etc.
    DK 2016 70528 A1
    In another alternative embodiment an impregnating agent may be applied. The impregnating agent may be based on any base material, for example a water based impregnating agent or other solvent free impregnating agents or even a solvent based impregnating agents known per se in the art.
    Description of the Drawing
    The invention will now be described with reference to the accompanying drawing in which
    Figure 1 illustrates how pressure builds up very slowly with steam at temperatures below 140°C.
    Figure 2 use of an inert gas as compared to steam
    Figure3a-3d illustrate readouts from the inventive method at different stages through the method.
    Detailed Description of the Invention
    The invention as already discussed above has two main goals, firstly to reduce the cycle time, i.e. the time that is necessary in order to thoroughly treat a batch of wood and secondly to improve the quality of such treatment, such that the batch of wood received an improved treatment and with less risk of damaging the wood structure during the treatment process.
    By replacing the traditional water based atmosphere, i.e. steam inside the treatment chamber by an inert gas, it is possible to separate pressure and temperature in the heating and cooling phase. In prior art methods a pressure is created by producing steam by heating up water. This process is time consuming since the increase in steam pressure lacks behind the temperature increase. A requirement in the treatment chamber is that the relative humidity must be kept above 85% RH in order to avoid or minimize damage to the wood. This delay causes a very slow increase in pressure as a function of temperature, particularly at low temperatures. At the same time requiring relative high energy consumption.
    In figure 1 is illustrated how pressure builds up very slowly with steam at temperatures below 140°C. From 30°C to 140°/170°C, which is the temperature range where most of the heating and cooling takes place for the inventive method and as such it can
    DK 2016 70528 A1 be seen that there is a distinctive difference in the inert gas’ ability to heat exchange with the wood as compared to steam (at least for the particular temperature range). As the temperature and pressure building is not connected with an inert gas it is possible to heat and cool the gas as fast as the system allows and control the pressure inside the treatment chamber separately.
    The use of an inert gas as compared to steam also increases the heat exchange with the wood such that it heats up faster. This is illustrated in figure 2 where it is clear that the rate of energy transfer between steam and wood as compared to nitrogen and wood is distinctively better for nitrogen and as such it is possible to transfer/exchange heat at a much higher rate using nitrogen (or an inert gas) than when using steam.
    As discussed above one of the main drawbacks with prior art methods is the high risk of creating cracks in the treated wood.
    These cracks emerge in any situation where the difference between the partial pressure inside the wood cells and the outside atmosphere is large enough to cause the cracks to develop. In the prior art heat treatment methods, it must be remembered that there is water present inside the wood, typically 10 - 14 %. As the steam atmosphere and the wood is heated up, steam pressure builds up both inside and outside of the wood. Cracks typically develop in the following situations:
    • In the heating phase, if the relative humidity (RH) of the steam atmosphere outside the wood becomes too low when heating up the atmosphere. In this situation, the partial pressure inside the wood may become larger than that outside the wood. Depending on the size of the relative overpressure inside the wood and other parameters such as wood species, cracks may result.
    • In the modification phase, when the hydrolysis of the hemicelluloses becomes exothermic. Depending on wood species, thickness of the boards being treated, moisture content and other parameters, temperature in the core of the wood quickly increases, typically 15 to 25 °C above the temperature of the surrounding steam atmosphere. This can lead to significant differences in relative pressure, illustrated in fig 1. In fig. 1, the pressure of steam in a closed system is shown as a function of temperature. Modification in prior art methods typically runs at 180°C, which corresponds to a pressure of 8,5 Bar at 85% RH. At 200 °C, the pressure is 13,2 Bar. Since the exotherm develops in the center of the wood, in this case a relative overpressure in the center of the wood of (13,28,5) 4,7 Bar develops very quickly. These thermodynamics created by the hemicelluloses exotherm represent a major cause for potential cracks and quality problems in prior art heat treatment methods.
    DK 2016 70528 A1 • In the cooling phase, if the temperature gradient in the wood becomes too steep. As illustrated in fig. 1, if the steam atmosphere is cooled too fast, especially in the beginning of the cooling phase when temperature is still high, the relative pressure in the steam will drop quickly relative to the still hot center of the wood. In this case a relative overpressure may build in the wood, leading to cracks.
    • Beside cracks, the presence of steam has also been reported to create other quality problems such as water stains and discoloring from condensates.
    All of the above mentioned dysfunctional partial pressure thermodynamics of prior art methods are effectively eliminated by the invention, in two ways:
    • In the initial vacuum and pressure phase, atmospheric air with its content of oxygen is removed from the wood cells and replaced by a condensed Nitrogen atmosphere at 10 Bar. At 10 Bar, the boiling point of water is approximately 180°C, so that the water in the wood is far below its boiling point. At 180°C, the pressure of Nitrogen has increased to approximately 15 Bar, so that the water in the wood is still kept below its boiling point. Thus the water present in the wood is far below its boiling point during the entire process, so that no significant partial steam pressure can build as temperature is increased.
    • In the hemicelluloses exotherm, Nitrogen will not build significantly higher partial pressure inside the wood, as the temperature in the center increases.
    Fig. Y below clearly illustrates that while steam pressure increases exponentially in the high temperature range, Nitrogen pressure only increases moderately in a linear manner. An increase in wood core temperature from 180 to 200°C will lead to an overpressure of (16,1 - 15,4) 0,7 Bar for Nitrogen, compared to 4,7 Bar for steam.
    In fig. 3a-3d, illustrating readouts from the inventive method at different stages through the method, it is clear to recognize the effects of the present invention.
    DK 2016 70528 A1
    权利要求:
    Claims (5)
    [1] 1. Thermo treatment process for wood comprising the following steps:
    a. Placing the wood batch to be treated in a treatment chamber;
    b. Exchanging the atmosphere inside the treatment chamber by evacuating the air, replacing the evacuated air by an inert gas atmosphere in gas form, at 8 to 12 bar pressure;
    c. Heating the inert gas atmosphere up to 165 to 175 °C,
    d. increasing the pressure in the inert gas atmosphere to 14-16 bar;
    e. maintaining the temperature in step c. and the pressure in step d. for from 90 to 150 minutes;
    f. cooling the inert gas atmosphere to a temperature of 20 to 35 °C
    g. retrieving the treated wood batch.
    [2] 2. Thermo treatment process for wood according to claim 1, wherein the inert gas is Nitrogen.
    [3] 3. Thermo treatment process for wood according to claim 1 or 2 wherein the process in steps c. and d. takes between 90 to 110 minutes.
    [4] 4. Thermo treatment process for wood according to claim 1 or 2 wherein in step d. or e. a mineral or organic oil may be applied to the batch of wood.
    [5] 5. Thermo treatment process for wood according to claim 1 or 2 wherein an impregnating agent is applied to the batch of wood in step d. or e.
    DK 2016 70528 A1
    类似技术:
    公开号 | 公开日 | 专利标题
    US10315331B2|2019-06-11|Thermo treatment process for wood
    KR102110787B1|2020-05-14|Process for the acetylation of wood and acetylated wood
    Inari et al.2006|XPS characterization of wood chemical composition after heat‐treatment
    CN101224593B|2010-06-09|Wood heat treatment method
    EP2091705B1|2018-12-05|Improvements relating to wood drying
    US2417995A|1947-03-25|Acetylation of lignocellulosic board materials
    AU2002231836B2|2006-01-05|Method for treating and drying of wood
    JP5965670B2|2016-08-10|Process for producing heat-treated wood
    Kong et al.2018|Development of schedule to steaming prior to drying and its effects on Eucalyptus grandis× E. urophylla wood
    Cheng et al.2014|Oil uptake percentage in oil-heat-treated wood, its determination by Soxhlet extraction, and its effects on wood compression strength parallel to the grain
    JP2013221667A|2013-10-28|Composite drying method and drying device for the same
    JP2017140757A|2017-08-17|Wood processing method
    Galyavetdinov et al.2016|Study of the speed of vacuum drying of pre-heated wood
    Song et al.2018|Effect of different boiling treatments on physical properties of cork from Quercus variabilis
    Ma et al.2015|EFFECTS OF MOISTURE ON DRYING RATE OF MICRO-EXPLOSION-PRETREATED FAST-GROWING POPLAR WOOD
    Sanya et al.2003|A new method for drying waterlogged wooden artefacts: Comparison of cyclical pressure drops with conventional methods
    Tarmian2019|CONTRIBUTION OF THERMAL DEGRADATION PRODUCTS TO THE HYDROXYL ACCESSIBLITY AND HYGROSCOPICITY OF THERMALLY MODIFIED WOOD
    Haghi et al.2013|Experimental Approach
    Kocaefe et al.2007|Preliminary study of thermal treatment effects on mold growth of selected Quebec wood species
    JP2005145035A|2005-06-09|Wood drying method
    WO2016013035A1|2016-01-28|Improved rapid rehydration method of vegetable and animal products
    AU2012203938B2|2014-07-10|Improvements relating to wood drying
    KR20100013726A|2010-02-10|Method for drying wood
    FR2931094A1|2009-11-20|Process for rapid drying of substrate made of material having wet wood, useful in building e.g. stairs and flooring, comprises completely immersing the substrate in bath of liquid resins having polyalkylene glycol
    CN109219504A|2019-01-15|Heat modification Wood products and the method for producing the product
    同族专利:
    公开号 | 公开日
    US20180015636A1|2018-01-18|
    RU2017125252A|2019-01-15|
    EP3272479B1|2019-06-12|
    CA2973204A1|2018-01-15|
    RU2017125252A3|2020-09-09|
    CA2973204C|2019-10-01|
    CN107618085A|2018-01-23|
    CN107618085B|2020-10-16|
    DK179238B1|2018-02-26|
    EP3272479A1|2018-01-24|
    RU2735769C2|2020-11-06|
    US10315331B2|2019-06-11|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    US4377040A|1979-04-25|1983-03-22|Rutgerswerke Aktiengesellschaft|Process for the modification of wood|
    CA1159643A|1980-11-25|1984-01-03|Eberhard Giebeler|Stabilization method|
    US20080178490A1|2007-01-26|2008-07-31|Masahiro Matsunaga|Method for drying lumber, method of impregnating lumber with chemicals, and drying apparatus|
    EP2196295A1|2008-12-04|2010-06-16|Fachhochschule Eberswalde|Wood, method and devices for its manufacture|
    JP2013180460A|2012-03-01|2013-09-12|Forestry & Forest Products Research Institute|Method for manufacturing heat-treated lumber|
    EP2998087A2|2014-09-01|2016-03-23|Royal Termo Træ ApS|Manufacturing method for a high durability, high insulating composite timber member and a composite timber member|
    US2435218A|1945-02-26|1948-02-03|Monie S Hudson|Apparatus and method for drying wood|
    US3395062A|1964-07-06|1968-07-30|Stapling Machines Co|Treatment of moisture-bearing fibrous materials|
    FR2786426B1|1998-11-27|2002-01-25|Arimpex Sarl|PROCESS FOR THE HEAT TREATMENT OF A LIGNOCELLULOSIC MATERIAL WITH THE REMOVAL OF OXYGEN IN THE GASEOUS PHASE|
    RU2186305C2|2000-07-04|2002-07-27|Научно-технический центр по разработке технологий и оборудования|Method of lumber drying|
    JP3562517B2|2001-08-30|2004-09-08|ヤマハ株式会社|Musical instrument and its manufacturing method|
    FR2846269B1|2002-10-28|2004-12-24|Jean Laurencot|PROCESS FOR TREATING A LOAD OF WOODY MATERIAL COMPOSED OF STACKED ELEMENTS, ESPECIALLY A LOAD OF WOOD, BY HEAT TREATMENT AT HIGH TEMPERATURE|
    RU2277045C2|2004-08-11|2006-05-27|Игорь Александрович Данченко|Method for thermal treatment of wood and device for its realization|
    WO2005114077A1|2004-09-21|2005-12-01|Joan Iglesias Vives|Method and machine for the sintering and/or drying of powder materials using infrared radiation|
    NL2000405C2|2006-12-22|2008-06-24|Willems Holding B V W|Method for making wood, wood product and its fixture sustainable.|
    CN100579741C|2007-01-23|2010-01-13|王益新|Ultrahigh temperature heat treatment method of wood|
    US20110020568A1|2007-03-28|2011-01-27|Igor Aleksandrovich Danchenko|Method for wood heat treatment and a device for carrying out said method|
    FI122117B|2008-05-21|2011-08-31|Ccm Power Oy|Process for drying organic piece-like material and dryer|
    KR101207875B1|2009-10-09|2012-12-05|배남길|a ventilating apparatus for building|
    RU2515008C1|2012-12-06|2014-05-10|Владимир Александрович Шутов|Method of production of thermo-impregnated wood and device for its implementation|
    CN103659973B|2013-11-26|2016-04-13|广西生态工程职业技术学院|A kind of quick-growing plantation Eucalyptus Wood high-temperature heat treatment process|
    CN103921325A|2014-04-22|2014-07-16|无锡宇盛厨卫有限公司|Method for anti-oxidation heat treatment of timber|
    DK179238B1|2016-07-15|2018-02-26|Wtt Holding Aps|A thermo treatment process for wood|DK179238B1|2016-07-15|2018-02-26|Wtt Holding Aps|A thermo treatment process for wood|
    CN109500974B|2018-11-16|2021-03-02|福建农林大学|Processing method of big-eyed wood slippers|
    CN109291192B|2018-11-22|2021-03-02|福建农林大学|Processing method of decorative plate with dimple pattern|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    DKPA201670528A|DK179238B1|2016-07-15|2016-07-15|A thermo treatment process for wood|DKPA201670528A| DK179238B1|2016-07-15|2016-07-15|A thermo treatment process for wood|
    EP17179688.1A| EP3272479B1|2016-07-15|2017-07-05|A thermo treatment process for wood|
    CN201710564646.6A| CN107618085B|2016-07-15|2017-07-11|Heat treatment process for wood|
    CA2973204A| CA2973204C|2016-07-15|2017-07-13|A thermo treatment process for wood|
    RU2017125252A| RU2735769C2|2016-07-15|2017-07-14|Method of thermal treatment of wood|
    US15/642,543| US10315331B2|2016-07-15|2017-09-14|Thermo treatment process for wood|
    [返回顶部]